Wednesday, January 20, 2010

North Dakota Proposed Benchmarks for Industrial Discharge

On January 15, the North Dakota Dept of Health released its proposed industrial stormwater discharge permit. One of the key requirements for North Dakota industrial dischargers is the requirement for stormwater monitoring and stormwater benchmarks. Selected industrial sectors require monitoring and need to meet benchmarks under the proposed permit, which is on public comment until February 15, 2010.

Wood and Paper Products
Applicability: Facilities with SIC code 2421-2426 (Sawing/Planning mills), 2491 (Wood
Preserving), 2493 (Reconstituted Wood Products), and 2631 (Paperboard Plants).

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Chemical Oxygen Demand 120 mg/L
• Phenols, Total 1.0 mg/L
• Arsenic, Total 0.1685 mg/L
• Copper, Total(1) 0.0636 mg/L


Chemical and Related Products
Applicability: Facilities with SIC code 281 (Industrial Inorganic Chemicals), 282 (Plastics and Synthetic Materials), 284 (Soaps and Detergents) and 287 (Agricultural Chemicals).

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Total Phosphorus 2.0 mg/L
• Ammonia (2) as N 15.0 mg/L
• Nitrates as Nitrogen 0.68 mg/l
• Chemical Oxygen Demand 120 mg/L
• Zinc, Total(1) 0.117 mg/L


Food and Related Products
Applicability: Facilities with SIC code 2011 (Meat Packing Plants), 2015 (Poultry Slaughtering and Processing), and 207 (Fats and Oils).

Benchmark Values

• Oil and Grease No visible sheen (15 mg/L)
• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Ammonia (2) as N 15.0 mg/L
• Nitrates as Nitrogen 0.68 mg/l
• 5-Day BOD 30 mg/L
• Chemical Oxygen Demand 120 mg/L
• Fecal Coliform 200 colonies/100mL


Primary Metal Industries
Applicability: Any facility classified as SIC code 33.

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Lead, Total(1) 0.0816 mg/L
• Cadmium, Total(1) 0.0159 mg/L
• Arsenic, Total(1) 0.1685 mg/L
• Copper, Total(1) 0.0636 mg/L
• Zinc, Total(1) 0.117 mg/L


Hazardous Waste Treatment, Storage and Disposal
Applicability: Facilities that treat, store or dispose of hazardous wastes.

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Chemical Oxygen Demand 120 mg/L
• Ammonia (2) as N 15 mg/L
• Arsenic, Total(1) 0.1685 mg/L
• Cadmium, Total(1) 0.0159 mg/L
• Lead, Total(1) 0.0816 mg/L
• Silver, Total(1) 0.0318 mg/L
• Cyanide, Total(1) 0.0636 mg/L
• Mercury, Total(1) 0.0024 mg/L
• Selenium, Total(1) 0.2385 mg/L


Landfills and Land Application
Applicability: Facilities associated with waste disposal at landfills, land application sites and open dumps that receive industrial waste.

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Total Suspended Solid 100 mg/L
• Chemical Oxygen Demand 120 mg/L
• Lead, Total(1) 0.0816 mg/L
• Oil and Grease No visible sheen (15 mg/L)

Automobile Salvage Yards
Applicability: Facilities engaged in dismantling or wrecking used motor vehicles for parts recycling/resale and for scrap; SIC code 5015.

Benchmark Values

• Oil and Grease No visible sheen (15 mg/L)
• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Chemical Oxygen Demand 120 mg/L
• Lead, Total(1) 0.0816 mg/L

Scrap Recycling Facilities
Applicability: Facility engaged in processing, reclaiming and distribution of metal scrap and other waste materials; SIC code 5093.

Benchmark Values

• Oil and Grease No visible sheen (15 mg/L)
• pH 6.0 – 9.0 S.U.
• Total Suspended Solids 100 mg/L
• Chemical Oxygen Demand 120 mg/L
• Copper, Total(1) 0.0636 mg/L
• Lead, Total(1) 0.0816 mg/L
• Zinc, Total(1) 0.117 mg/L


Air Transportation
Applicability: Regional and Primary commercial Airports and Air Force Bases

Benchmark Values

• pH 6.0 – 9.0 S.U.
• Ammonia(2) as N 15.0 mg/L
• Nitrates as Nitrogen 0.68 mg/l
• 5-Day BOD 30 mg/L
• Chemical Oxygen Demand 120 mg/L


Notes:
1 Hardness dependent; values given are based on a water hardness of 100 mg/L as CaCO3.
2 Ammonia is pH dependent; value given is based on a pH of 8.0 s.u.


Since the 1980s, the U.S. Environmental Protection Agency (EPA) has collected industry-sector data on stormwater discharge. The linked presentation provides a comparison of these historic industrial stormwater results to the many of the ADEQ stormwater benchmark concentrations. The results are discussed in context of which stormwater benchmark parameters have a higher potential for exceedance of benchmark values. This presentation also discusses which of the industrial sectors have a higher potential for exceedance of their specific benchmark values.

Note: NDDH uses the same benchmark concentrations used by EPA and many other States; although the this linked presentation was specific to Minnesota, the analysis and conclusions apply to Norh Dakota.

Link to presentation slides:

Industrial Stormwater Benchmarks – Comparison of New Minnesota Benchmark Concentrations To Historic Industry-specific Testing Results


Caltha LLP provides expert consulting services to public and private sector clients nationwide to address water quality standards, wastewater permitting and assessing potential impacts of chemicals in the aquatic environment.

Caltha LLP Aquatic Toxicology / WQ Standards Services Website




Monday, January 11, 2010

Iowa Lake Water Quality Standards - Secchi disk and Chlorophyll

The Iowa DNR is proposing a rule that sets water quality criteria necessary to protect for recreational uses in lakes. In summary, the rule contains two criteria: Secchi depth of at least one meter and chlorophyll-a not to exceed 25 ug/l. The two criteria must be met at least 75% of the time in order for the lake to be considered to support recreation such as swimming.

The proposed rule 61.3(4) is as follows:

61.3(4) Lake criteria. So that the recreational uses listed in 61.3(1)“b”(1) through 61.3(1)“b”(3) can be supported, the following criteria are applicable to all lakes that have a mean depth of three meters or greater.
a. Transparency. The transparency of the lake as measured with a Secchi Disk shall be one meter or more in at least 75 percent of the measurements taken.
b. Chlorophyll-a. The concentration of chlorophyll-a in 75 percent of the samples analyzed shall not exceed 25 micrograms per liter (μg/l).
c. Water sampling used to determine whether a lake meets the transparency and chlorophyll-a criteria must meet the following:
(1) A minimum of nine sample results are required.
(2) At least three of the samples must be taken from the deepest part of the lake.
(3) All samples must be taken during the months of May through September.
(4) At least three sampling events must be conducted in any one summer recreation season.
(5) Samples must be taken in at least three summer seasons in a five-consecutive-year period.
d. Nitrogen and phosphorus concentrations are among several variables affecting lake transparency and chlorophyll-a levels; however, individual lake and watershed characteristics determine the precise amount of nutrients that can be tolerated within a lake while still attaining the above recreational use criteria. For this reason, nutrient reduction targets will be determined on a case-by-case basis as a result of lake-specific monitoring and data analysis. Lake nutrient response models, such as those used to establish Total Maximum Daily Loads for lakes with transparency or chlorophyll-a impairments, or other appropriate scientific methods will be utilized for this purpose.

Caltha LLP provides expert consulting services to public and private sector clients nationwide to address water quality standards, wastewater permitting and assessing potential impacts of chemicals in the aquatic environment.

Caltha LLP Aquatic Toxicology / WQ Standards Services Website



Monday, January 4, 2010

Revised Washington Benchmarks for Industrial Stormwater Discharge

Effective January 1, 20010, the Washington Department of Ecology has issued new benchmark concentrations for industrial stormwater discharges. Dischargers subject to the revised State industrial stormwater discharge permit must collect samples of stormwater discharge at least quarterly. Different levels of Corrective Action are required if dischargers exceed any of their respective benchmarks over one or more quarters.

The revised benchmarks are:

All Facilities:
Parameter Benchmark Value
Turbidity 25 NTU
pH Between 5.0 and 9.0
Oil Visible Sheen (Yes/No)
Total Copper Western WA: 14 ug/L, Eastern WA: 32 ug/L
Total Zinc 117 ug/L

Industrial Sector Specific Benchmarks:
Chemical and Allied Products ( SIC 28), Food and Kindred Products (SIC 20)
BOD5 30 mg/L
Nitrate/Nitrite 0.68 mg/L
Phosphorus 2.0 mg/L

Primary Metals (SIC 33), Metals Mining (SIC 10), Automobile Salvage and Scrap Recycling (5015 and 5093), Metals Fabricating (SIC 34)
Total Lead 81.6 ug/L
Total Petroleum Hydrocarbons 10 mg/L

Hazardous Waste Treatment, Storage and Disposal Facilities and Dangerous Waste Recyclers
COD 120 mg/L
Ammonia 2.1 mg/L
TSS 100 mg/L
Total Arsenic 150 ug/L
Total Cadmium 2.1 ug/L
Total Cyanide 22 ug/L
Total Lead 81.6 ug/L
Total Magnesium 64 ug/L
Total Mercury 1.4 ug/L
Total Selenium 5.0 ug/L
Total Silver 3.8 ug/L
Total Petroleum Hydrocarbons 10 mg/L

Air Transportation (SIC 45)
Ammonia 2.1 mg/L
BOD5 30 mg/L
COD 120 mg/L
Nitrate/Nitrite 0.68 mg/L

Timber Product Industry (SIC 24), Paper and Allied Products (SIC 26)
COD 120 mg/L
TSS 100 mg/L

Caltha LLP provides expert consulting services to public and private sector clients nationwide to address water quality standards, wastewater permitting and assessing potential impacts of chemicals in the aquatic environment.

Caltha LLP Aquatic Toxicology / WQ Standards Services Website